METHODS FOR RAPID DETECTION OF POLLUTANTS IN THE AQUATIC ENVIRONMENT

Authors

DOI:

https://doi.org/10.20535/2218-930032025348693

Keywords:

aquatic environment monitoring, ammonium, analysis methods, dissolved oxygen, nitrates, nitrites, water quality indicators

Abstract

Global changes in geopolitics and economics, directly or indirectly, significantly affect the state of the environment, in particular, water resources. In addition to the mining and energy industry, the chemical industry and agriculture, significant changes in the ecological state of the environment are caused by man-made accidents and military conflicts, which lead to uncontrolled emissions of a large number of pollutants into the air, soil and water environment. While air pollution is instantaneous and noticeable, water pollution is characterized by a more “delayed effect” due to the dilution of pollutants, absorption by plants and accumulation in bottom silt deposits, which increases the duration of the negative impact and over time can lead to repeated pollution of the environment (for example, due to the shallowing of surface water sources). Monitoring of the aquatic environment has its own characteristics compared to the implementation of air monitoring and can include both the determination of the content of dissolved gases (for example, dissolved oxygen), and the determination of the content of various ionic and molecular forms. The latter is especially important if these compounds are formed as a result of the ingress of toxic compounds into the water (including those of military origin – fuel, combustion products of explosives), and therefore can serve as a kind of markers for taking immediate action to eliminate man-made threats. The development of methods for determining dissolved gases and soluble nitrogen compounds – ammonium, nitrites and nitrates – is aimed not only at increasing sensitivity, but also at expanding functionality in real-world conditions. Modern methods for directly determining dissolved substances in water, which allow for real-time monitoring, and which involve the use of sensor systems, remote sensing using non-contact methods and the so-called Internet of Things, are analyzed.

References

Ahmed, S.; Lee, C.; Tsang, Y. F. Removal of Organic Micropollutants by Advanced Oxidation Processes in Wastewater Treatment Plants. J. Environ. Chem. Eng. 2025, 13, 115916. https://doi.org/10.1016/j.jece.2025.115916

Boyer, E. W.; Hornberger, G. M.; Bencala, K. E.; McKnight, D. M. Response of Streamwater Chemistry to Different Sources of Nitrate in a Mountain Watershed. JAWRA J. Am. Water Resour. Assoc. 2015, 51 (2), 262–275. https://doi.org/10.1111/1752-1688.12386

Chaudhary, S.; Passi, A.; Jindal, S.; Goyal, K. LC–MS/MS: A Powerful Tool for Modern Analytical Science: Fundamentals, Techniques, Applications and Innovations. J. Liq. Chromatogr. Relat. Technol. 2025, 48 (11–15), 1–11. https://doi.org/10.1080/10826076.2025.2491475

Derzhavne ahentstvo vodnykh resursiv Ukrainy. Vodohospodars’ki orhanizatsii. https://www.davr.gov.ua/vodogospodarskiorganizacii (accessed June 27, 2025)

EcoWater Monitoring: Derzhavne ahentstvo vodnykh resursiv Ukrainy. http://monitoring.davr.gov.ua/EcoWaterMon/GDKMap/Index (accessed June 27, 2025).

Fang, T.; Li, H.; Bo, G.; Lin, K.; Yuan, D.; Ma, J. On Site Detection of Nitrate plus Nitrite in Natural Water Samples Using Smartphone Based Detection. Microchem. J. 2021, 165, 106117. https://doi.org/10.1016/j.microc.2021.106117

Gómez Sánchez, J.; Pacheco, A. A Simple and Rapid Method for Determination of Heavy Metals in Environmental Water Samples. J. Elem. 2019, 24 (3), 1848–1859. https://doi.org/10.5601/jelem.2019.24.3.1848

Jaywant, S. A.; Arif, K. M. Remote Sensing Techniques for Water Quality Monitoring: A Review. Sensors 2024, 24 (24), 8041. https://doi.org/10.3390/s24248041

Kumar, A.; Sharma, V.; Singh, R. Novel Chromatographic Approaches for Quantifying Environmental Contaminants. Chem. Biodivers. 2024, 21, e202403451. https://doi.org/10.1002/cbdv.202403451

Kumar, A.; Singh, R.; Sinha, R.; Patel, S. Characterization of Groundwater Nitrate Contamination in India: A Case Study. Appl. Water Sci. 2016, 6, 357–365. https://doi.org/10.1007/s13201-016-0488-y

Lee, S.; Park, S. The Impact of Water Pollution on Urban Livelihoods: Evidence from South Korea. SSRN Electron. J. 2022, 1–18. https://doi.org/10.2139/ssrn.4210575

Li, H.; Fang, T.; Bo, G.; Lin, K.; Yuan, D.; Ma, J. Determination of Nitrate and Nitrite in Water Using Colorimetric Methods Coupled with Microfluidic Devices. Microchem. J. 2025, 192, 112683. https://doi.org/10.1016/j.microc.2025.112683

Li, X.; Zhang, Y.; Wang, J.; Liu, H. Advanced Techniques for Water Quality Monitoring Using IoT Devices. Environ. Monit. Assess. 2025, 197, 213. https://doi.org/10.1007/s43832-025-00213-1

Lu, Z.; Liao, K.; Zhang, G.; Wang, J.; Ma, X. Assessing the Occurrence and Distribution of Perfluoroalkyl Acids in Groundwater. Environ. Sci. Technol. 2013, 47 (24), 14062–14070. https://doi.org/10.1021/es300419u

Malm, L.; Liigand, J.; Aalizadeh, R.; et al. Quantification Approaches in Non-Target LC/ESI/HRMS Analysis: An Interlaboratory Comparison. Anal. Chem. 2024, 96 (41), 16215–16226. https://doi.org/10.1021/acs.analchem.4c02902

Moorcroft, M. J.; Davis, J.; Compton, R. G. Detection and Determination of Nitrate and Nitrite: A Review. Talanta 2001, 54 (5), 785–803. https://doi.org/10.1016/S0039-9140(01)00323-X

Richardson, S. D.; Kimura, S. Y. Water Analysis: Emerging Contaminants and Current Issues. Anal. Chem. 2020, 92 (1), 473–505. https://doi.org/10.1021/acs.analchem.9b05269

Schnetger, B.; Lehners, C. Determination of Nitrate plus Nitrite in Small Volume Marine Water Samples Using Vanadium(III) Chloride as a Reduction Agent. Mar. Chem. 2014, 160, 91–98. https://doi.org/10.1016/j.marchem.2014.01.010

Singh, R.; Kumar, A.; Patel, S. Environmental Monitoring of Heavy Metals Using Spectrophotometric Techniques. Environ. Monit. Assess. 2015, 187, 4687. https://doi.org/10.1007/s10661-015-4687-z

Snelder, T. H.; Booker, D. J. Development of Indicators for Water Resources in New Zealand: River Health and Nutrient Fluxes. Nat. Hazards 2013, 65, 1435–1450. https://doi.org/10.2166/nh.2013.105

Srinivasan, V.; Kumar, A.; Sharma, R. Assessment of Water Quality in Urban Reservoirs: A Case Study. Water Resour. Manag. 2015, 29, 3895–3907. https://doi.org/10.1007/s11269-015-1109-5

Valiente, N.; Gómez Alday, J. J.; Jirsa, F. Spectrophotometric Determination of Nitrate in Hypersaline Waters after Optimization Based on Box–Behnken Design. Microchem. J. 2018, 145, 951–958. https://doi.org/10.1016/j.microc.2018.12.007

Vazquez Campos, S.; Dotto, G. L. Silver Nanoparticles and Metallic Silver Interfere with the Griess Reaction: Reduction of Azo Dye Formation via a Competing Sandmeyer Like Reaction. Chem. Res. Toxicol. 2017, 30 (4), 1030–1037. https://doi.org/10.1021/acs.chemrestox.6b00280

Zhang, L.; Mendoza, A.; Ma, J.; Alvarez, P. J. J. Influence of Natural Organic Matter on the Photochemical Degradation of Antibiotics in Water. Water Res. 2015, 79, 164–172. https://doi.org/10.1016/j.watres.2014.12.005

Zhang, M.; Huang, Y.; Yuan, D.; Zhu, Y.; Li, H.; Fang, T. Simultaneous Determination of Nitrite and Nitrate in Seawater Using Reverse Flow Injection Analysis Coupled with a Long Path Length Liquid Waveguide Capillary Cell. Environ. Sci. Technol. 2014, 48, 13082–13090. https://doi.org/10.1021/acs.est.4c14209

Zhang, Y.; Li, X.; Wang, J. Recent Advances in Electrochemical Sensors for Environmental Analysis. Talanta 2018, 190, 187–201. https://doi.org/10.1016/j.talanta.2018.08.028

Zhang, Y.; Li, X.; Wang, J.; Chen, H.; Liu, Q. Development of a Wearable Sensor for Nitrate Detection in Environmental Water. Sensors 2024, 24, 8041. https://doi.org/10.3390/s24248041

Downloads

Published

2025-12-28

How to Cite

Kosohin, O., Linyucheva, O., Kosohin, A., Amburtseva, O., & Kosogina, I. (2025). METHODS FOR RAPID DETECTION OF POLLUTANTS IN THE AQUATIC ENVIRONMENT. WATER AND WATER PURIFICATION TECHNOLOGIES. SCIENTIFIC AND TECHNICAL NEWS, 43(3), 3–14. https://doi.org/10.20535/2218-930032025348693

Issue

Section

WATER QUALITY AND ANALYSIS METHODS