PROSPECTS FOR THE USE OF METAL OXIDES IN NANOFORM FOR INDUSTRIAL WASTEWATER TREATMENT

Authors

DOI:

https://doi.org/10.20535/2218-930012025325892

Keywords:

metal oxides, nanomaterials, photocatalysis, sorption, wastewater, water purification

Abstract

The article presents the results of a theoretical study on the prospects for the use of metal oxides in nanoform for industrial wastewater treatment. The growing problem of water pollution by inorganic compounds, especially heavy metals (Pb²⁺, Cd²⁺, Hg²⁺, Cr⁶⁺), as well as phosphates, nitrates, and sulfates, creates a demand for innovative and eco-friendly purification technologies. Conventional treatment methods often lack effectiveness under conditions of high pollutant concentrations or complex wastewater composition. Nanostructured metal oxides, due to their high surface area, ion-exchange capacity, and catalytic activity, offer promising solutions for pollutant removal. The study provides an analytical overview of recent scientific literature on the properties, synthesis methods, and application of TiO₂, ZnO, Fe₃O₄, MnO₂, CuO, and Al₂O₃ in purification processes. The mechanisms of sorption, photocatalysis, precipitation, and complexation are discussed in detail. Influencing factors such as pH, particle morphology, temperature, pollutant concentration, and contact time are analyzed. Special attention is paid to the development of composite materials and surface-functionalized nanomaterials, which enhance selectivity, reusability, and stability in aggressive environments. The potential environmental impact, regeneration strategies, and barriers to large-scale application are also considered. The conclusions highlight the relevance of nanostructured metal oxides in the development of efficient, scalable, and sustainable technologies for water purification, in line with modern ecological and industrial challenges. Further interdisciplinary research is recommended to address safety, standardization, and cost-effectiveness aspects.

References

Zhang, W.; He, R.; Zhang, Z. Application of titanium dioxide nanoparticles in wastewater treatment: A review. Journal of Environmental Chemical Engineering, 2020, 8, 104364. https://doi.org/10.1016/j.jece.2020.104364

Raliya, R.; Tarafdar, J.C.; Biswas, P. Enhancing the efficiency of wastewater treatment using nanomaterials. Environmental Science: Nano, 2016, 3, 1121–1130. https://doi.org/10.1039/C6EN00192E

Rojas, S.; Horcajada, P. Metal–organic frameworks for the removal of emerging organic contaminants in water. Chemical Reviews, 2020, 120, 8378–8415. https://doi.org/10.1021/acs.chemrev.9b00700

Wang, Y.; Zhou, D.; Wang, H.; Zhang, J. Removal of Cr from aqueous solutions by magnetic Fe₃O₄ nanoparticles. Water Science and Technology, 2018, 77, 2444–2452. https://doi.org/10.2166/wst.2018.187

Li, X.; Li, Y.; Meng, Q. Photocatalytic degradation of industrial wastewater using ZnO nanomaterials. Materials Today: Proceedings, 2021, 47, 327–333. https://doi.org/10.1016/j.matpr.2021.05.243

Zhao, G.; Li, J.; Ren, X.; Chen, C.; Wang, X. Few-layered graphene oxide nanosheets as superior sorbents for heavy metal ion pollution management. Environmental Science & Technology, 2011. 45, 1045–10462. https://doi.org/10. 1021/es202690b

Kaur, R.; Singh, J.; Rawat, M. Nano-based approaches for treatment of wastewater containing heavy metals: A review. Chemosphere, 2021. 1322-1333. https://doi.org/10.1016/j.chemosphere.2021.132233

Zhang, J.; Yu, J.; Zhang, Y.; Li, Q.; Gong, J.R. Visible light photocatalytic H₂-production activity of CuS/ZnS nanocomposites. Applied Catalysis B: Environmental, 2011. 102, 451–458. https://doi.org/10.1016/j.apcatb.2010.12.016

Ghosh, A.; Biswas, S.; De, G. MnO₂ nanosheets as efficient adsorbent for Pb²⁺ and Cr⁶⁺ ions. RSC Advances, 2016. 6, 102020–102027. https://doi.org/10. 1039/C6RA23020F

Mousa, M.A.; El-Dek, S.I.; Ahmed, M.A. Efficient removal of cadmium from water using magnetic Fe₃O₄ nanoparticles: Mechanisms and reusability. Journal of Industrial and Engineering Chemistry, 2015. 27, 102–110. https://doi.org/10.1016/j.jiec.2014.12.006

Qu, X.; Alvarez, P.J.J.; Li, Q. Applications of nanotechnology in water and wastewater treatment. Water Research, 2013. 47, 3931–3946. https://doi.org/10.1016/j.watres.2012.09.058

Gupta, V.K.; Ali, I. Environmental water: Advanced treatment technologies. Amsterdam: Elsevier. 2012. 450 p.

Wang, S.; Peng, Y. Natural zeolites as effective adsorbents in water and wastewater treatment. Chemical Engineering Journal, 156, 11–24. https://doi.org/10.1016/j.cej.2009.10.029

Singh, S.; Barick, K.C.; Bahadur, D. Surface engineered magnetic nanoparticles for removal of heavy metals from water. Journal of Hazardous Materials, 2010, 192, 1539–1547. https://doi.org/10.1016/j.jhazmat.2011.06.073

Liu, L.; Yang, Y.; Wang, Q.; Liu, L.; Li, J. Synthesis of CuO nanoparticles for removal of Pb²⁺ and Cd²⁺ from wastewater: Adsorption mechanism and reusability. Journal of Molecular Liquids, 2019. 301, 112417. https://doi.org/10.1016/j.molliq.2019.112417

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Published

2025-09-10

How to Cite

Kochubei, O., Sovhira, S., & Dushechkina, N. (2025). PROSPECTS FOR THE USE OF METAL OXIDES IN NANOFORM FOR INDUSTRIAL WASTEWATER TREATMENT. WATER AND WATER PURIFICATION TECHNOLOGIES. SCIENTIFIC AND TECHNICAL NEWS, 41(1), 46–53. https://doi.org/10.20535/2218-930012025325892

Issue

Section

WASTEWATER TREATMENT