ENVIRONMENTAL PROBLEMS CAUSED BY THE USE OF REVERSE OSMOSIS MEMBRANE ELEMENTS, AND WAYS TO SOLVE THEM
DOI:
https://doi.org/10.20535/2218-930012022259491Keywords:
reverse osmosis spiral membrane elements, desalination, fouling, reuse, utilizationAbstract
More than 70 percent of our planet is covered with water. And yet water is a scarce resource, and it is our future. According to the World Wildlife Fund, 1.1 billion people do not have access to it, and 2.7 billion experience a shortage of drinking water at least once a year. By 2025, two-thirds of the world's population may face water shortages.
The shortage of drinking water and the search for renewable resources are of the most important problems in the modern world, the solution of which is directed to considerable intellectual and financial resources. Reverse osmosis is one of the most common technologies for obtaining high-quality drinking water. Technological solutions constantly improve the process of reverse osmosis and reverse osmosis spiral wound membrane elements used, science and business go hand in hand. But the price of this progress is the annual generation of a large amount of waste generated from used reverse osmosis roll membrane elements, which are usually sent to the landfill, while there are no technological solutions for their disposal.
This work provides information on the available amount of such waste in the world and the dynamics of its growth in order to assess the scale of environmental damage that occurs as a result.
The work collected information about the market of reverse osmosis spiral wound membrane elements in the world, and directions of their use. The structure, composition of components and technical characteristics of reverse osmosis spiral wound membrane elements are considered in detail, which makes it possible to evaluate the ways and possibilities of their utilization. The problems of surface contamination due to various types of fouling are considered. The main attention in the work is given to the reasons that cause the formation of waste. Based on the collected data, the scale of annual waste generation, which is formed due to spent reverse osmosis roll membrane elements, was analyzed. The possibility of reusing reverse osmosis spiral wound membrane elements and the main methods of their safe disposal are also considered. Summarizing the work carried out, recommendations were made on ways to solve the problem.
References
Adel, M.; Nada, T.; Amin, S.; Anwar, T.;. Mohamed A.A. Characterization of fouling for a full-scale seawater reverse osmosis plant on the Mediterranean sea: membrane autopsy and chemical cleaning efficiency. Groundwater for Sustainable Development. 2022, 16, 100704. https://doi.org/10.1016/j.gsd.2021.100704
Agnihotri, B.; Sharma, A.; Gupta A.B. Characterization and analysis of inorganic foulants in RO membranes for groundwater treatment. Desalination. 2020, 491, 114567. https://doi.org/10.1016/j.desal.2020.114567
Aliyu, U.M.; Rathilal, S.; Isa, Y.M. Membrane desalination technologies in water treatment: A review. Water Practice and Technology. 2018, 13, 738 – 752. https://doi.org/10.2166/wpt.2018.084
Al-Salem, S. M.; Lettieri, P.; Baeyens J. Recycling and recovery routes of plastic solid waste (PSW): A review. Waste Management. 2009, 29, 2625–2643. https://doi.org/10.1016/j.wasman.2009.06.004
Asadollahi, M.; Bastani, D.; Musavi S. A. Enhancement of surface properties and performance of reverse osmosis membranes after surface modification: a review. Desalination. 2017, 420, 330 – 383. https://doi.org/10.1016/j.desal.2017.05.027
Contreras-Martínez, J.; García-Payo, C.; Arribas, P.; Rodríguez-Sáez, L.; Lejarazu-Larrañaga, A.; García-Calvo, E. Khayet, M. Recycled reverse osmosis membranes for forward osmosis technology. Desalination. 2021, 519, 115312. https://doi.org/10.1016/j.desal.2021.115312
Cran, M.J.; Bigger, S.W.; Gray S.R. Degradation of polyamide reverse osmosis membranes in the presence of chloramine. Desalination. 2011, 273, 58 – 63. https://doi.org/10.1016/j.desal.2011.04.050
Dai, D.; Chen, Y.; Zhu, W.; Shi, L.;. Cheng, R.; Zheng, X.; Li, J. Recycling of spent RO membranes: review of research status and progress. Chemical Industry and Engineering Progress. 2021, 40, 2290 – 2297. https://doi.org/0.16085/j.issn.1000-6613.2020-0906
Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste and repealing certain directives; 32008L0098.; Off. J. Eur. Union L13: 2008; 3–30.
Donose, B. C.; Sukumar, S.; Pidou, M.; Poussade, Y.; Keller, J.; Gernjak W. Effect of pH on the ageing of reverse osmosis membranes upon exposure to hypochlorite. Desalination. 2013, 309, 97–105. https://doi.org/10.1016/j.desal.2012.09.027
García-Pacheco, R.; Landaburu-Aguirre, J.; Lejarazu-Larrañaga, A.; Rodríguez-Sáez, L.; Molina, S.; Ransome, T.; García-Calvo, E. Free chlorine exposure dose (ppm•h) and its impact on RO membranes ageing and recycling potential. Desalination. 2019, 457, 133-143. https://doi.org/10.1016/j.desal.2019.01.030
García-Pacheco, R.; Landaburu-Aguirre, J.; Molina, S.; Rodríguez-Sáez, L.; Teli, S. B.; García-Calvo, E. Transformation of end-of-life RO membranes into NF and UF membranes: Evaluation of membrane performance. J. Membr. Sci. 2015, 495, 305-315. https://doi.org/10.1016/j.memsci.2015.08.025
Goh, P.S.; Lau, W.J.; Othman, M.H.D.; Ismail A.F. Membrane fouling in desalination and its mitigation strategies. Desalination. 2018, 425, 130 – 155. https://doi.org/10.1016/j.desal.2017.10.018
Gonzalez-Gil, G.; Behzad, A. R.; Farinha, A. S. F.; Zhao, C.; S. S. Bucs; Nada, T.; Das, R.; Altmann, T.; Buijs, P. J.; Vrouwenvelder, J.S. Clinical autopsy of a reverse osmosis membrane module. Front. Chem. Eng. 2021, 3, 683379. https://doi.org/10.3389/fceng.2021.683379
Hailemariam, R. H.; Woo, Y. C.; Damtie, M. M.; Kim, B. C.; Park K. D.; Choi, J. S. Reverse osmosis membrane fabrication and modification technologies and future trends: A review. Adv. Colloid Interface Sci. 2020, 276, 102100. https://doi.org/10.1016/j.cis.2019.102100
Jiang, S.; Li, Y.; Ladewig, B. P. A review of reverse osmosis membrane fouling and control strategies. Sci. Total Environ. 2017, 595, 567 – 585. https://doi.org/10.1016/j.scitotenv.2017.03.235
Kang, G.D.; Gao, C.J.; Chen, W.D.; Jie, X.M.; Cao, Y.M.; Yuan, Q. Study on hypochlorite degradation of aromatic polyamide reverse osmosis membrane. J. Membr. Sci. 2007, 300, 165–171. https://doi.org/10.1016/j.memsci.2007.05.025
Khaless, K.; Achiou, B.; Boulif, R.; Benhida R. Recycling of spent reverse osmosis membranes for second use in the clarification of wet-process phosphoric acid. Minerals. 2021, 11, https://doi.org/10.3390/min11060637
Landaburu-Aguirre, J.; García-Pacheco, R.; Molina, S.; Rodríguez Rabadan, L.; Saez, E.; García-Calvo J. Fouling prevention, preparing for re-use and membrane recycling. Towards circular economy in RO desalination. Desalination. 2016, 393, 16–30. https://doi.org/10.1016/j.desal.2016.04.002
Lawler, W.; Bradford-Hartke, Z.; Cran, M.J.; Duke, M.; Leslie, G.; Ladewig B.P.; Le-Clech, P. Towards new opportunities for reuse, recycling and disposal of used reverse osmosis membranes. Desalination. 2012, 299,103–112. https://doi.org/10.1016/j.desal.2012.05.030
Ling, R.; Yu, L.; Pham, T. P. T.; Shao, J.; Chen, J. P.; Reinhard, M. The tolerance of a thin-film composite polyamide reverse osmosis membrane to hydrogen peroxide exposure. J. Membr. Sci. 2017, 524, 529 – 536. https://doi.org/10.1016/j.memsci.2016.11.041
Ling, R.; Shao, Chen, J.P.; Reinhard, M. Iron catalyzed degradation of an aromatic polyamide reverse osmosis membrane by free chlorine. J. Membr. Sci. 2019, 577, 205 – 211. https://doi.org/10.1016/j.memsci.2019.02.010
Mitchenko, T. Ye. et al. The series of editions. The world of modern water treatment. Methods and materials; NGO WaterNet, 2019. ISBN 978-966-97940-2-4.
Moradia, M.R.; Pihlajamäkia, A.; Hesampoura, M.; Ahlgrenb, J.; Mänttäria, M. End-of-life RO membranes recycling: Reuse as NF membranes by polyelectrolyte layer-by-layer deposition. J. Membr. Sci. 2019, 584, 300-308. https://doi.org/10.1016/j.memsci.2019.04.060
Othman, N. H.; Alias, N. H.; Fuzil, N.S.; Marpani, F.; Shahruddin, M. A Review on th e Use of Membrane Technology Systems in Developing Countries. Membranes. 2021, 12, 1-37. https://doi.org/10.3390/membranes12010030
Ouali, S.; Loulergue, P.; Biard, P. F.; Nasrallah, N.; Szymczyk A. Ozone compatibility with polymer nanofiltration membranes. J. Membr. Sci. 2021, 618, 118656. https://doi.org/10.1016/j.memsci.2020.118656
Ould, M. E; Penate Suarez, D. B.; Vince, F.; Jaouen, P.; Pontie M. New Lives for Old Reverse Osmosis (RO) Membranes. Desalination. 2010, 253, 62–70. https://doi.org/10.1016/j.desal.2009.11.032
Paula, E. C. de; Amaral, M. C. S. Environmental and economic evaluation of end-of-life reverse osmosis membranes recycling by means of chemical conversion. J. Cleaner Prod. 2018, 194, 85–93. https://doi.org/10.1016/j.jclepro.2018.05.099
Pontie, M.; Awad, S.; Tazerout, M.; Chaouachi, O.; Chaouachi B. Recycling and energy recovery solutions of end-of-life reverse osmosis (RO) membrane materials: a sustainable approach. Desalination. 2017, 423, 30–40. https://doi.org/10.1016/j.desal.2017.09.012
Qasim, M.; Badrelzaman, M.; Darwish, N.N.; Darwish, N.A.; Hilal N. Reverse osmosis desalination: A state-of-the-art review. Desalination. 2019, 459, 59 – 104. https://doi.org/10.1016/j.desal.2019.02.008
Tyvonenko, A.V.; Homaniuk O.V.; Mitchenko, T.Ye.; Vasilyuk S.L. Ecological analysis of the market of reverse osmotic spiral wound membrane. Resources of natural waters in Carpathian region/Problems of protection and rational exploatation: 20TH International Scientific-Practical, L`viv, May 26–27 2022.
Varin, K.J.; Lin, N.H.; Cohen, Y. Biofouling and cleaning effectiveness of surface nanostructured reverse osmosis membranes. J. Membr. Sci. 2013, 446, 472–481. https://doi.org/10.1016/j.memsci.2013.06.064
Verbeke, R.; Eyley, S.; Szymczyk, A.; Thielemans, W.; Vankelecom Ivo F.J. Controlled chlorination of polyamide reverse osmosis membranes at real scale for enhanced desalination performance. J. Membr. Sci. 2020, 611, 118400. https://doi.org/10.1016/j.memsci.2020.118400
Yu, L.; Ling, R.; Chen, J.P.; Reinhard M. Quantitative assessment of the iron-catalyzed degradation of a polyamide nanofiltration membrane by hydrogen peroxide. J. Membr. Sci. 2019, 588, 117154. https://doi.org/10.1016/j.memsci.2019.05.078
Downloads
Published
Issue
Section
License
Copyright (c) 2022 A. V. Tyvonenko, T. Ye. Mitchenko, S. L. Vasilyuk
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
The ownership of copyright remains with the Authors.
Authors may use their own material in other publications provided that the Journal is acknowledged as the original place of publication and National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute” as the Publisher.
Authors are reminded that it is their responsibility to comply with copyright laws. It is essential to ensure that no part of the text or illustrations have appeared or are due to appear in other publications, without prior permission from the copyright holder.
WPT articles are published under Creative Commons licence:- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under CC BY-NC 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal. The use of the material for commercial purposes is not permitted.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.